Facile one-step aqueous-phase synthesis of porous PtBi nanosponges for efficient electrochemical methanol oxidation with a high CO tolerance

Abstract

• Facile, green, and templet-free approach is developed for one-step preparation of PtBi nanosponge. • PtBi nanosponges enhanced the methanol oxidation activity and stability than Pt and Pt/C. • The formation mechanism of PtBi nanosponges is attributed to oriented attachment growth. • PtBi nanosponges showed nanosponge structure with 3D interconnected pores. • PtBi nanosponges revealed high CO tolerance than Pt/C and Pt. Deliberate control in the composition and morphology of Pt-based catalysts is an efficient route for enhancing the methanol oxidation reaction (MOR). Herein we developed a facile method for rational one-step aqueous-phase synthesis of PtBi nanosponges with tunable composition, based on the prompt reduction of an aqueous solution of Pt and Bi precursors using NaBH 4 . Mechanistically, the high-reduction power of NaBH 4 formed multiple small colloidal PtBi nanocrystals (NCs), which coalesce together to reduce their interfacial energy resulting in oriented attachment growth. The fabrication process is simple, quick (2 min), productive, and free of surfactants or organic solvents. PtBi nanosponges showed 3D network-like architectures with a rough surface and interconnected pores (mesopore and macropore). The MOR mass (specific) activity of Pt 67 Bi 33 , 1.8 A/mg Pt (15.4 mA cm −2 ), outperformed Pt 78 Bi 22 , Pt, and Pt/C, by 2.3 (1.2), 4.8 (3.6), and 5.1 (24.7) times, respectively besides greater stability and CO tolerance. This method could be extended to synthesize other binary Pt-based catalysts for various electrocatalytic applications.