Facile green synthesis of zero-valent iron nanoparticles using barberry leaf extract (GnZVI@BLE) for photocatalytic reduction of hexavalent chromium

Abstract

In this study, zero-valent iron (GnZVI) was synthesized using barberry leaf extract (GnZVI@BLE). The physicochemical properties of the final products were characterized by FT-IR, SEM, TEM, and EDS techniques. The results of TEM analysis showed that the obtained iron zero-valent nanoparticles with a diameter between 20 and 40 nm and shell-core structures were successfully synthesized. The results of FT-IR confirmed the presence of various functional groups. The photocatalytic activity of synthesized nanoparticles was investigated by reduction of hexavalent chromium. Laboratory data showed that the presence of GnZVI@BLE as a nanocatalyst in the photocatalytic process could be reduction the hexavalent chromium (Cr (VI)). Photocatalytic data revealed that, when the dosage of nanoparticles was 0.675 g/L, the reduction efficiency of hexavalent chromium was 100%. The kinetics of the reaction follows a pseudo-second-order equation. The constant of reaction rate was 0.4 at pH 2 and 0.5 g/L concentration of GnZVI@BLE.