Facile fabrication of semi-IPN hydrogel adsorbent based on quaternary cellulose via amino-anhydride click reaction in water

Abstract

Clean and safe water resources play a key role in environmental safety and human health. Recently, hydrogels have attracted extensive attention due to their non-toxicity, controllable performance, and high adsorption. Herein, a semi- interpenetrating network hydrogel (semi-IPN-Gel) adsorbent based on quaternary cellulose (QC) was prepared by the amino-anhydride click reaction between maleic anhydride copolymer and polyacrylamine hydrochloride (PAH), and its adsorption properties for Eosin Y were studied. First, a binary copolymer (PAM) of acrylamide and maleic anhydride was synthesized by free radical polymerization. Then, the PAM, QC and PAH were dissolved in water, and the pH of the solution was adjusted to alkaline. Semi-IPN-Gel was successfully prepared by fast anhydride-amino click reaction. The preparation conditions of hydrogels were optimized by single-factor experiments. Finally, taking Eosin Y as a model pollutant, the adsorption performance of Eosin Y was studied. The factors influencing the adsorption capacity of the absorbents such as initial concentration of the Eosin Y, temperature, the amount of absorbent, ionic strength and pH of the Eosin Y solutions were investigated. And adsorption data were analyzed via the kinetic model and the isothermal model, indicating that the adsorption process of the hydrogel is a single layer chemisorption process.