Facile fabrication of organic superhydrophobic corn silk-derived cellulose acetate nanofiber for the effective sequestration of oil from oil-water mixture.

Abstract

Oil spills and subsequent cleanup by oil-water separation remain a global concern. For the first time, corn silk-derived cellulose acetate (CSCA) and polyacrylonitrile (PAN) composite nanofiber are reported to create a superhydrophobic oil-water sequestration membrane. CA : PAN solutions with various PAN concentrations were evaluated for viscosity and conductivity. A CSCA nanofiber membrane was fabricated through electrospinning, which was superhydrophobic and oleophilic in water. Scanning electron microscope, energy-dispersive spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction, and thermogravimetric analysis/differential scanning calorimetry were used to analyze the membrane's morphological features. CSCA nanofibers formed a highly spherical bead with a maximum contact angle of 156° (>120°) in pure water solutions, demonstrating their superhydrophobicity. This study found that membranes can remove oil from oil-water mixtures and emulsions, as gravity is the only force required for propelling the system. Mineral oil had the highest oil sorption capability (908%), while toluene had the lowest (664%). For mineral oil-water mixtures, the CSCA membrane has the greatest separation flux at a maximum of 442 L/m2/h and the best separation efficiency at up to 99.67%. These findings provide strong support for using an as-prepared CSCA nanofiber membrane as a viable reusable oil sorbent in oil spill cleaning.