Facile fabrication of magnetically recyclable Fe3O4/BiVO4/CuS heterojunction photocatalyst for boosting simultaneous Cr(VI) reduction and methylene blue degradation under visible light

Abstract

It is a challenging problem that develops a low-cost, efficient and sustainable technology in order to remove heavy metals and organic contaminants in the practical wastewater. Herein, a novel recyclable Fe3O4/BiVO4/CuS (FBCu) heterojunction photocatalyst was facilely fabricated by a method, coating CuS nanoparticles on the surface of Fe3O4 and BiVO4 simultaneously. FBCu composite not only has the ability to degrade Cr(VI) or methylene blue (MB) alone under visible light irradiation, but also exhibits higher photocatalytic ability in simultaneously removing Cr(VI) and MB mixed pollutants. The superior photocatalytic performance of FBCu is related to the formation of p-n heterojunction, which extends the spectral response and facilitates the efficiency of charge carriers separation and utilization. Moreover, FBCu exhibits satisfactory properties of reusability and stability after five cycling experiments in the Cr(VI)-MB coexistence system. Furthermore, the detailed mechanism for simultaneous removal of mixed pollutants was proposed and verified by DRS results, photoelectrochemical analysis, scavenger experiments and electron spin resonance determination. This work provides a recyclable photocatalyst with eco-friendliness and multifunctional applications in water pollution.