Facile fabrication of cross-linked carbon nanofiber via directly carbonizing electrospun polyacrylonitrile nanofiber as high performance scaffold for supercapacitors

Abstract

Cross-linked carbon nanofiber (CLCNF) was successfully prepared by directly carbonizing electrospun polyacrylonitrile (PAN) nanofiber. Comparing to non-cross-linked carbon nanofiber (NCLCNF) obtained via carbonizing of pre-oxidation PAN nanofiber, CLCNF shows better conductivity owing to its cross-linked structure. Then CLCNF was used as scaffold to support polyaniline (PANi) nanorods for supercapacitor electrode material. The hierarchical CLCNF/PANi composite displays a capacity of 206Cg−1 at 0.5Ag−1 with excellent rate capability (remains 49% even at 800Ag−1), which is much higher than that of NCLCNF/PANi composite (17%). More interestingly, supercapacitor device based on CLCNF/PANi composite achieves 75.3% capacity retention after 10000 charge-discharge cycles at 10Ag−1, suggesting excellent cycle stability. All these experimental results indicate that this method for fabricating CLCNF is a substantial advancement towards the practical applications of carbon nanofiber in energy conversion and storage field.