Abstract
The domino reactions of ethyl 3-oxo-4-(arylsulfonyl)butanoates with aromatic aldehydes in a 2:1 molar ratio in the presence of a catalytic amount of ammonium acetate furnished densely functionalized cyclohexa-1,4-dienes stereoselectively, while the domino reactions of ethyl 3-oxo-4-(arylsulfonyl)butanoates, aromatic aldehydes, and ammonium acetate in a 1:2:2 molar ratio afforded highly functionalized 1,2,5,6-tetrahydropyridines stereoselectively.
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