Facile Conversion of Polystyrene Waste into an Efficient Sorbent for Water Purification.

Abstract

In this work, we convert a plastic waste, i.e., polystyrene (PS), into a sorbent by a simple sulfonation process. The sulfonation time was optimized and the structures of the resulting sulfonated polystyrene (SPS) was characterized by field emission scanning electron microscopy, energy-dispersive X-ray and contact angle tests. The results showed that the sulfonation time of 7 h can introduce abundant sulfonic groups and preserve the self-standing structure. Additionally, the SPS has a three-dimensional porous structure and hydrophilic surface because of the presence of numerous sulfonic groups, which could serve as effective binding sites for immobilizing varying pollutants. Furthermore, as a proof-of-concept, the adsorption performance of the SPS foams was evaluated using three pollutants, namely Pb2+, lysozyme and methylene blue. The adsorption isotherms were fitted by the Langmuir and Freundlich models, while the kinetics of the adsorption processes were analyzed using the pseudo-first-order, pseudo-second-order and intraparticle diffusion equations. It was found that the adsorption isotherms of Pb2+ and lysozyme can be better described by the Langmuir model, leading to maximum equilibrium adsorption uptakes of 10.5 and 15.7 mg g-1 for the adsorption of Pb2+ and lysozyme, respectively. Importantly, the pollutant-saturated SPS is readily regenerated by acid washing, and the recovered sorbents exhibit outstanding cyclic performance. The abundant availability of feedstock, facile preparation and regeneration processes render the SPS foams a promising sorbent for practical applications.