Facies evolution and stratigraphic correlation in the early Oligocene Tard Clay of Hungary as revealed by maceral, biomarker and stable isotope composition

Abstract

Hydrocarbon source rocks (i.e. Tard Clay Formation), containing type-II organic matter, were deposited in the Hungarian Paleogene Basin during Lower Oligocene. A major contribution of aquatic organisms (green algae, dinoflagellates, Chrysophyte algae) and minor inputs from macrophytes and land plants to organic matter accumulation is indicated by n-alkane distribution patterns, composition of steroids, and δ13C of hydrocarbon biomarkers. Microbial communities included heterotrophic bacteria, cyanobacteria, chemoautotrophic bacteria, as well as green sulphur bacteria. The presence of methanotrophic bacteria is indicated by 13C-depleted hop-17(21)-ene. Higher inputs of terrestrial organic matter occurred during deposition of the lower and uppermost units of the Tard Clay Formation. The terpenoid hydrocarbon composition argues for angiosperm-dominated vegetation in the area of the Hungarian Paleogene Basin. Diterpenoid hydrocarbons, derived from the resins of conifers, are about 2–3‰ enriched in 13C compared to the angiosperm biomarkers.Environmental conditions changed from marine to brackish, accompanied by oxygen-depletion in the lower parts of the water column. Organic carbon accumulation during this period was a consequence of stagnant bottom water conditions in the Hungarian Paleogene Basin due to salinity stratification. This is indicated by low pristane/phytane ratios (varying from 0.27 to 1.44), enhanced ratios of dimethylated versus trimethylated MTTCs (0.14–0.59), and the presence of aryl isoprenoids (from 0.4 to 14.1 μg/g TOC). A major marine incursion is evidenced by stable isotope ratios of organic matter and carbonates. In the uppermost member of the Tard Clay, a transition from brackish towards normal marine conditions is proposed.Up to 3 anoxic cycles are recognized in the drill core sections, separated by minima in pristane/phytane ratios and maxima in the depth trends of di-/tri-methylated MTTCs and aryl isoprenoid concentrations. In combination with the position of maxima of δ13C of carbonate and organic matter and an abrupt decrease in perylene concentrations, the cycles can be used for intra-formational correlation of the Tard Clay.