Abstract
In the title compound, [Co(C6H4NO2)3], the CoIII ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C—H⋯O hydrogen bonds.
Highlights
In the title compound, [Co(C6H4NO2)3], the Co ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands
The ligands are coordinated in a chelate fashion, forming three five-membered rings
Translationally related complex molecules are organized into columns along [001] via
Summary
Irina A. Golenia,a Alexander N. Boyko,a Natalia V. Department of Chemistry, Kiev National Taras Shevchenko University, Volodymyrska Street 64, 01601 Kiev, Ukraine, bDepartment of Chemistry, University of Joensuu, PO Box 111, FI-80101 Joensuu, Finland, and cDepartment of General
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