Fabrication of Strongly Fluorescent Quantum Dot−Polymer Composite in Aqueous Solution

Abstract

For the first time, we report a simple method to fabricate a quantum dot (QD)−polymer composite completely via aqueous media from synthesis of QDs to formation of composite. A series of l-cysteine-capped CdTe QDs with tunable emission from green to red were prepared by using hydrothermal techniques, and the corresponding average particle sizes were estimated to be from 2.5 to 4.1 nm. After incorporating these CdTe QDs into the waterborne polyurethane (WPU) prepolymer aqueous suspension, we obtained a transparent nanocomposite film by casting and evaporating. The optical properties of the aqueous CdTe QDs solution and CdTe−WPU composites were investigated by UV−vis absorption and photoluminescence (PL). The results indicate that the quantum yield (QY) and the photochemical stability of the CdTe QDs in both CdTe−WPU aqueous complex and solid composite are enhanced significantly, because of a thicker and more compact passivating layer formed on the surface of CdTe QDs via the reaction between the groups of −...