Fabrication of Silver-Decorated Graphene Oxide Nanohybrids via Pulsed Laser Ablation with Excellent Antimicrobial and Optical Limiting Performance.

Abstract

The demand for metallic nanoparticle ornamented nanohybrid materials of graphene oxide (GO) finds copious recognition by virtue of its advanced high-tech applications. Far apart from the long-established synthesis protocols, a novel laser-induced generation of silver nanoparticles (Ag NPs) that are anchored onto the GO layers by a single-step green method named pulsed laser ablation has been exemplified in this work. The second and third harmonic wavelengths (532 nm and 355 nm) of an Nd:YAG pulsed laser is used for the production of Ag NPs from a bulk solid silver target ablated in an aqueous solution of GO to fabricate colloidal Ag-GO nanohybrid materials. UV-Vis absorption spectroscopy, Raman spectroscopy, and TEM validate the optical, structural, and morphological features of the hybrid nanomaterials. The results revealed that the laser-assisted in-situ deposition of Ag NPs on the few-layered GO surface improved its antibacterial properties, in which the hybrid nanostructure synthesized at a longer wavelength exhibited higher antibacterial action resistance to Escherichia coli (E. coli) than Staphylococcus aureus (S. aureus) bacteria. Moreover, nonlinear optical absorption (NLA) of Ag-GO nanohybrid was measured using the open aperture Z-scan technique. The Z-scan results signify the NLA properties of the Ag-GO hybrid material and have a large decline in transmittance of more than 60%, which can be employed as a promising optical limiting (OL) material.