Fabrication of Magnetically Inorganic/Organic Superhydrophobic Fabrics and Their Applications.

Abstract

In order to solve the problem caused by oil spills and organic solvent contamination, novel magnetically inorganic/organic superhydrophobic fabrics are fabricated via a facile method. Cotton fabrics are immersed in a mixture of functionalized Co0.2Mg0.8Fe2O4 (FCMFO) nanoparticles, vinyl-terminated polydimethylsiloxane (VPDMS), trimethylolpropane triacrylate, and 2-hydroxy-2-methylpropiophenone before UV irradiation for 100 s to obtain the multifunctional superhydrophobic fabrics with magnetic property. The coated fabrics show excellent superhydrophobicity, and the water contact angle is 157.1° when the mass ratio of FCMFO nanoparticles to VPDMS is 0.3. These superhydrophobic fabrics have high oil/water separation efficiency (98.7% for dichloromethane/water) and high oil flux (71,506 L·m-2·h-1 for dichloromethane/water). Even after 20 separation cycles, oil/water separation efficiency and oil flux maintain 96.4% and 64,012 L·m-2·h-1, respectively. Furthermore, the magnetic property of these superhydrophobic fabrics could be used in the separation of oil from water. Moreover, the superhydrophobic fabrics possess exceptional self-cleaning performance, mechanical durability, chemical stability, and flame retardancy. These multifunctional superhydrophobic fabrics are potential for wide applications.