Fabrication of lignin-derived mesoporous carbon/magnesium oxide composites for microwave-assisted isomerization of glucose in water

Abstract

A series of mesoporous carbon/magnesium oxide composites (LDMC@MgO-x) with different Mg doping ratios were synthesized by using alkali lignin as the carbon source, potassium chloride as the salt template and magnesium nitrate as the catalytic site precursor, respectively. The BET, FTIR, SEM, and TEM analyses indicated that the as-prepared LDMC@MgO-x possessed a unique hierarchical porous structure with high specific surface area, rich functional groups, and uniformly distributed MgO nanoparticles. Among them, LDMC@MgO-20%, as an optimized base catalyst, could realize effective isomerization of glucose with a maximum fructose yield of 34.4 % in water at 130 °C for only 5 min under microwave assistance. In addition, the activation energy of glucose isomerization catalyzed by LDMC@MgO-20% was estimated to be about 43.6 kJ·mol−1, which was lower than that of most Lewis acid-catalyzed systems.