Fabrication of graphene-based magnetic carbon composites derived from iron cobalt metal-organic framework as dual-band electromagnetic wave absorbers

Abstract

The fabrication of advanced magnetic carbon electromagnetic wave (EMW) absorbers derived from metal-organic framework (MOF) with thin thickness, wide bandwidth, strong absorption strength and low filling ratio remains a huge challenge. In this paper, CoFe2O4/CoFe/C/Graphene composites were prepared by a simple two-step way of solvothermal reaction and carbonization treatment. The results of micromorphology analysis revealed that as the carbonization temperature increased, the obtained carbon frameworks changed from a spindle shape to dodecahedron-like shape and finally to a tile shape, and the carbonization temperature had a notable influence on the electromagnetic parameters and EMW absorption properties of the magnetic carbon composites. It should be noted that the obtained CoFe2O4/CoFe/C/Graphene composites exhibited comprehensive excellent EMW absorption performance when the carbonization temperature was 750.0 ℃ and the filling radio was only 15.0 wt%, namely the effective absorption bandwidth reached up to 4.8 GHz and the optimal minimum reflection loss was −40.2 dB at a thickness of 2.06 mm. A distinct dual-band (C band and Ku band) absorption feature was observed when the thickness exceeded or equaled 4.5 mm. Furthermore, the underlying electromagnetic dissipation mechanisms were also elucidated. Therefore, our results could provide a valuable reference for preparing excellent magnetic carbon EMW absorbers derived from MOF.