Fabrication of free-standing octagon-shaped carbon nanofibre assembly for electrical actuation of shape memory polymer nanocomposites

Abstract

Purpose – The purpose of this paper is a study aimed at overcoming the interface issue between nanopaper and polymer matrix in shape-memory polymer (SMP) composite laminates caused by their large dissimilarity in electrical/thermal conductive properties. The study attempted to develop an effective approach to fabricate free-standing carbon nanofibre (CNF) assembly in octagon shape formation. The structure design and thermal conductive performance of the resulting octagon-shaped CNF assembly were optimised and simulated. Design/methodology/approach – The CNF nanopaper was prepared based on a filtration method. The SMP nanocomposites were fabricated by incorporating these CNF assemblies with epoxy-based SMP resin by a resin-transfer modelling technique. Thermal conductivity of the octagon-shaped CNF assembly was simulated using the ANSYS FLUENT software for structure design and optimisation. The effect of the octagon-shaped CNF on the thermomechanical properties and thermally responsive shape-memory effect of the resulting SMP nanocomposites were characterised and interpreted. Findings – The CNF template incorporated with SMP to achieve Joule heating triggered shape recovery at a low electric voltage of 3-10 V, due to which the electrical resistivity of SMP nanocomposites was significantly improved and lowered to 0.20 O·cm by the CNF template. It was found that the octagon CNF template with 2 mm width of skeleton presented a highest thermally conductive performance to transfer resistive heat to the SMP matrix. Research limitations/implications – A simple way for fabricating electro-activated SMP nanocomposites has been developed by using an octagon CNF template. Low electrical voltage actuation in SMP has been achieved. Originality/value – The fabricated CNF template, the structure design and analysis of dynamic thermomechanical properties of SMP are novel.