Abstract
Formation of favorable interface between a lithium metal electrode and a solid electrolyte by inserting a lithium thin film contributes to reproducible lithium dissolution and deposition in rechargeable bulk-type all-solid-state cells. A lithium symmetrical cell with a Li2S-P2S5 solid electrolyte was galvanostatically cycled at room temperature. A bulk-type solid-state Li/S cell exhibited a good cycle performance with a capacity higher than 900mAhg−1 at 0.064mAcm−2 (0.03C).
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