Abstract

Conductive plastics are attracting more and more interest in electronics due to their light weight and inability to rust, which are common problems associated with metals. The field of conducting plastics is not new. Much work has been done to impart electrical conductivity to mechanically strong polymers such as polypropylene, polycarbonate and epoxies, etc. However there is a need to fabricate more flexible and elastic conductive polymers such as conducting silicone rubbers for use in various applications. In this work silicone rubbers reinforced with conductive fillers have been fabricated for use as sensors in textiles to detect the resistance change produced by stretching or relaxing. The variations of electrical resistance have been investigated by stretching and releasing the strands of conductive rubbers as a function of time. Two types of silicone rubbers—addition cured and condensation cured—were compounded with different electrically conductive fillers, among which carbon fibers have shown the best results. The carbon fibers improved the electrical conductance of the rubbers, even in very low weight percentages. The increasing concentration of fillers decreases the elasticity of the rubber. In order to keep the original properties of silicones, the filler concentration was kept as low as possible to produce a significantly detectable signal. The fabricated compounds were analyzed for their mechanical properties by stress strain curves. Such materials find their applications in electronics, antistatic applications, sports and the automotive industry where they can be used as deformation sensors.

Highlights

  • Silicones are polymers containing silicon along with carbon, hydrogen, oxygen, and sometimes other elements

  • To prepare electrically conducting silicone compounds, first E1 and E2 were compounded with the electrically conductive fillers using an electrical mixer for 5 minutes followed by the addition of hardeners in the mixing ratios recommended by the manufacturers (Table 1) and a further mixing for 5 minutes

  • Conductive silicone rubbers have been produced by adding conductive fillers to the rubbers during processing

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Summary

Introduction

Silicones are polymers containing silicon along with carbon, hydrogen, oxygen, and sometimes other elements. The research work presented in this contribution aims to develop a flexible and elastic conductive polymer with resistance in kOhm range which upon stretching and releasing gives almost the same values of resistance Such material has applications in the textile industry, where it can act as an electrical resistance sensor which changes if the textile is stretched or relaxed. Was made to keep the concentration of fillers at the level where they decrease the silicone resistance while keeping the silicones as close to the original as possible These textiles based on such conductive silicone rubbers have potential applications in the field of sports and automobile industry where they can detect various deformations present in structures e.g. shoes, gloves, etc

Electrical Resistance
Mechanical Analysis
Silicone Rubbers
Electrically Conductive Fillers
Fabrication of Conductive Silicone Rubbers
Conclusions
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