Fabrication of Durable, Chemically Stable, Self-Healing Superhydrophobic Fabrics Utilizing Gellable Fluorinated Block Copolymer for Multifunctional Applications.

Abstract

Limited durability and complex materials restrict the application of superhydrophobic fabrics in daily life. In this work, gellable fluorinated block copolymer poly(dodecafluoroheptyl methacrylate)-block-poly(3-(triethoxysilyl)propyl methacrylate) (PDFMA-b-PTEPM) was used to fabricate adhesive-free superhydrophobic poly(ethylene terephthalate) (PET) fabrics via a simple dip-coating technology and sol-gel reaction. The growth of silica nanoparticles builds up a rough hierarchical structure and provides sol-gel reaction sites of PTEPM segments. The grafting of block copolymer significantly reduced the surface free energy of the fabrics, resulting in an excellent superhydrophobicity with a water contact angle of 160.2°. Benefiting from extensive chemical bond grafting and cross-linking of the PTEPM segment, the fabric exhibits excellent durability in mechanical abrasion, chemical treatment, and washing. The coating has withstood 50 sandpaper abrasion cycles and 400 soft friction cycles and can maintain superhydrophobic properties in various solvents, freezing and a wide pH range. These superhydrophobic fabrics with a long life span possess self-cleaning, anti-icing, oil-water separation, and self-healing capabilities. The multifunctional fabrics developed in this study are durable and easy to produce, possessing the potential for applications in industry and daily life.