Abstract
The CaOZrO2TiO2Al2O3B2O3SiO2 glass, a potential glaze, solder and immobilizer of high-level radioactive wastes, was prepared from the powder batches of CaOZrO2TiO2 (C5ZT, subscripts are molar ratios) with the additives of B2O3, SiO2 and Al2O3 and at a firing temperature of ∼ 1200°C. Upon heating (10°C/min) for differential thermal analysis, all the glasses went through a glass transition event at ∼ 640°C (peak temperature) and then two devitrification events at ∼ 800 and 900°C, which caused the formation of m-ZrO2 and ZrO2-derived phases (predominantly zirconolite, CaZrTi2O7), respectively. Glass-ceramics were further fabricated from the glass slabs by one-stage heating at ∼ 900°C, which caused first the cellular layer and then spherulitic clusters of ZrO2 derivatives. When the glass-ceramics were subjected to prolonged annealing, the ZrO2-derived phases always survived while borate, silicate and other phases appeared. The selection of zirconia-related phases during devitrification are discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.