Fabrication of Ag@Ag2O-MnOx composite nanowires for high-efficient room-temperature removal of formaldehyde

Abstract

Efficient removal of pollutant formaldehyde (HCHO) at room temperature using transition-metal oxides remains a huge challenge to date. Manganese oxide can oxidize formaldehyde, however, how to control the valence states of manganese is the key to further improve the removal efficiency. We have successfully prepared porous manganese oxide nanowires (MnOx NWs) with large surface area and multiple valence states of manganese using simple electrospinning followed by thermal calcination and potassium permanganate solution post-treatment (C/S process). The contents of trivalent and tetravalent manganese increased significantly after C/S process. Moreover, the composition of silver oxide coated silver nanowires (Ag@Ag2O NWs) is realized by assistance with oxygen plasma, which further enhanced high valence manganese. The formaldehyde removal efficiency by Ag@Ag2O–MnOx composite nanowires can reach 93.7%. The high-efficient catalytic activity is confirmed to attribute to the higher surface area of composite nanowires, the high-valence manganese and the silver oxide for oxidation of formaldehyde.