Abstract

Preliminary XRD, IR, Raman and SEM data indicate that porous glass-ceramic monoliths (pgc-LVCP) with skeleton of V(PO3)3 and Ca3(VO4)2 with three-dimensional network structure using an original Li2O-V2O3-CaO-P 2O5 glass as precursor was obtained. The pgc-LVCP is a promising porous host for integrated chemical systems because the Ca3(VO4)2 has ferroelectric and luminophor properties while V(PO3)3 exhibits magnetic properties associated with high degree of mechanical, chemical and thermal stability.

Highlights

  • Porous materials are extremely important in the fields of nanotechnology, integrated chemical systems, and cooperative interactions in reactions performed in confined environment.[1,2,3,4]

  • The size, the morphology and the reactivity of the particle will depend on the dimensions, morphology, texture and chemical nature of the surface of pores

  • The crystalline phases of the glass-ceramic before and after acid leaching were characterized by X-ray powder diffraction (XRD), infrared (IR) and Raman spectroscopies

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Summary

Introduction

Porous materials are extremely important in the fields of nanotechnology, integrated chemical systems, and cooperative interactions in reactions performed in confined environment.[1,2,3,4] There is an increasing interest in designing and developing porous materials with stable porous texture for high-temperature separation and catalytic applications.[5]. Glass-ceramic samples (gc-LVCP) were prepared by a thermal treatment of the glass plates at 530 oC for 20 h (nucleation step) and subsequently at 600 oC for 12 h (crystallization step; the crystallization temperature, Tc, is equal to 600 oC for g-LVCP for a heating rate of 10 oC min-1).

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