Fabrication of a nanoporous dual‐electrode system for electrochemical redox cycling

Abstract

AbstractNanoporous electrodes are promising tools for highly sensitive electrochemical detection of molecules by redox cycling. In here, we report on a novel approach for the on‐chip fabrication of nanoporous dual‐electrode systems. The fabrication is based on template assisted dry etching into an electrode–insulator–electrode structure using a nanoporous alumina film as a mask. The mask itself is patterned by directly anodizing an aluminum layer on top of the chip. Homogeneous growth of the alumina nanopores on a wafer scale is achieved by adding a titanium intermediate film between the top electrode and the aluminum substrate as a stopping layer. The resulting electrodes are separated by approximately 100 nm and have pore diameters in the range of 30–50 nm. Thus they are ideally suited for redox cycling experiments based on fast diffusion of molecules between the electrodes. Integrating this process into microfabricated electrode structures promises to yield a stable and sensitive electrochemical sensor platform.magnified image Redox cycling scheme for a nanoporous dual‐electrode system. The close distance of anode and cathode provides a short diffusion path of oxidized and reduced molecules, as depicted by the arrows. The inlet shows a close‐up of the molecules within a pore. Different colours indicate different oxidation states.