Abstract
New cross-linked conjugated polydiacetylenes with stable columnar order have been fabricated by using hydrogen-bonded discotic liquid crystals (DLCs) containing photoreactive diacetylene and acrylate moieties. The polymerizable DLC exhibiting columnar mesophase has been prepared simply through hydrogen bonding between a phloroglucinol core and pyridine derivatives containing two photoreactive groups. Photopolymerization of the hydrogen-bonded DLCs in the LC state yielded cross-linked conjugated polydiacetylenic columns in which the diacetylene and acrylate groups were selectively polymerized. Our controlled methodology will provide a promising way to fabricate supramolecular π-functional polymeric materials for plastic optoelectronic devices.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
