Fabrication and Testing of Crop Waste Ceiba pentandra Shell Powder Reinforced Biodegradable Composite Films.

Abstract

Ceiba pentandra shell powder (CPSP) biowaste is chosen as a biofiller combined with poly(vinyl alcohol) (PVA) as a matrix to make biofilms to increase the exploitation of biowaste materials and reduce the use of plastic materials. FTIR plots indicated no significant chemical reaction or formation of new functional groups during interaction between PVA and CPSP. XRD diffractograms showed that the crystallinity index (35.3, 38.6, 42.3, 46.4, and 48.5%) and crystalline size (18.14, 20.89, 23.23, 24.87, and 26.34 nm) of biofilms increased with CPSP loading (5-25 wt %). The PVA/CPSP films are thermally stable up to 322 °C. The peak highs of AFM images showed that the films' surface roughness gradually increased from 94.75 nm (5 wt % CPSP) to 320.17 nm (25 wt % CPSP). The FESEM micrographs clarify the homogeneous distribution of CPSP in the PVA matrix. Tensile strength and tensile modulus are noticeably increased by 26.32 and 37.92%, respectively, as a result of the loading of CPSP from 5 to 20 wt % in the PVA matrix. The PVA/CPSP films outperform pure PVA films in UV shielding (350-450 nm). The 59% weight loss of films was estimated during 60 days of burial. The fabricated biofilms maintained their suitable structural, thermal, morphological, and mechanical properties. Additionally, they exhibited consistent performance in ultraviolet (UV) barrier, opacity, water absorption, water vapor permeability, soil burial, and antimicrobial characteristics over time. Overall, PVA/CPSP (5-25 wt %) films are biodegradable and have promising applications as good packaging materials.