Abstract

In this paper, lightweight carbon/carbon fiber composite thermal field insulation materials were fabricated by the process method of long carbon fiber airflow netting-needle punching forming felt-resin impregnation-molding curing-high-temperature carbonization and graphitization. The microscopic morphology, conductivity, bending strength, and thermal conductivity of carbon/carbon fiber composites were measured by using the scanning electron microscope (SEM), four probes, electronic universal testing machine, and thermal analyzer. The results show that the long carbon fiber in the carbon/carbon fiber composite forms a three-dimensional structure of X-Y-Z with a density of 0.16 ± 0.02 g/cm3, which makes the composite material have excellent thermal insulation performance at high temperature, and the conductivity is 1452.4 S/m (plane direction) and 182.8 S/m (perpendicular to the plane direction), the compressive strength is 0.2 MPa (plane direction) and 1.31 MPa (perpendicular to the plane direction), the bending strength is 0.24 MPa (plane direction) and 1.1 MPa (perpendicular to the plane direction), and the thermal conductivity is 0.076 W/(mK) (25°C) and 0.17 W/(mK) (1200°C), respectively. The above process methods and test results will provide the application of the carbon/carbon fiber composite in the solar polysilicon furnace, single crystal silicon furnace, semiconductor furnace, sapphire furnace, fiber drawing furnace, and high-end metallurgical heat treatment furnaces, as well as applications in other high-temperature insulation environments, and also provide some suggestions in these insulation applications.

Highlights

  • Most of the growth of the silicon crystal, silicon carbide crystal, and sapphire crystal needs to be carried out at a temperature higher than 1500°C

  • Our team cooperated with Hangzhou Vulcan New Materials Technology Co., Ltd. to solve a series of technological problems and formed a set of innovative preparation process of high temperature resistance, heat preservation, and lightweight carbon/carbon fiber composite. e innovation lies in the following two points. (a) Long carbon fiber is used to prepare lightweight carbon/carbon fiber composite, and the thermal insulation performance of the prepared carbon/carbon fiber composite is better than that of the short-cut fiber. (b) e direct use of carbon fiber airflow netting-needle forming felt process instead of preoxidized fiber airflow netting-needle punching-carbonization process reduces the process steps and avoids product shrinkage due to carbonization

  • The degree of graphitization of the carbon/carbon fiber composite is related to the high temperature resistance of the carbon/carbon fiber composite. is paper will measure the graphitization of the material through the study of electrical conductivity. e mechanical properties of the lightweight carbon/carbon fiber composite are related to the dimensional stability of the carbon/carbon composite, which is related to the thermal field stability of the high-temperature furnace. erefore, the mechanical properties of the lightweight carbon/carbon fiber composite have been studied. e effects of the X-Y-Z three-dimensional structure on the thermal conductivity, electrical conductivity, and mechanical properties of the lightweight carbon/carbon fiber composite were studied

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Summary

Introduction

Most of the growth of the silicon crystal, silicon carbide crystal, and sapphire crystal needs to be carried out at a temperature higher than 1500°C. Lightweight carbon/carbon fiber composites can be prepared from carbon fiber materials (or fiber felts) by impregnating resin-molding curing-high temperature graphitization. Compared with the traditional carbon fiber felt materials, lightweight carbon/ carbon fiber composites have higher mechanical strength, easy installation, high temperature steam erosion resistance, and long service life due to the adhesion of carbon to carbon fiber felt. Our team cooperated with Hangzhou Vulcan New Materials Technology Co., Ltd. to solve a series of technological problems and formed a set of innovative preparation process of high temperature resistance, heat preservation, and lightweight carbon/carbon fiber composite. E mechanical properties of the lightweight carbon/carbon fiber composite are related to the dimensional stability of the carbon/carbon composite, which is related to the thermal field stability of the high-temperature furnace. It is expected to provide some advice for the application of high-temperature equipment such as crystal growth and high-temperature heat treatment

Experimental
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