Abstract
Graphitic carbon nitride quantum dots (CNQDs) with a high quantum yield (up to 43%) were synthesized by incorporating the unique organic functional group of barbituric acid into the framework of the carbon nitride structure by supramolecular pre-organization. The CNQDs were introduced onto the surface of basic zinc carbonate (BZC) by co-precipitation. The resulting CNQDs/BZC composite showed that the degradation efficiency of tetracycline was 2.4 times higher than that of ZnO. The Z-scheme mechanism for the as-prepared sample was proposed for the enhanced photocatalytic degradation rate. The ˙O2- and ˙OH radicals played major roles due to the suitable bandgap. Finally, the formation and possible photocatalytic mechanisms of the CNQDs/BZC composite are proposed.
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