Fabrication and Characterizations of Superhydrophobic Surface with Superior Corrosion Inhibition on Q345b Steel Substrate

Abstract

AbstractIn this work, a coherent and cost‐effective method is developed to achieve superhydrophobicity and excellent corrosion resistance on Q345B steel surfaces. The method involves sequential etching with hydrochloric acid and hydrofluoric acid, passivation with potassium permanganate, treatment with bis‐(γ‐triethoxysilylpropyl)‐tetrasulfide (KHSi69，BT), and modification with hydrophobic SiO2 nanoparticles. The effects of etching and passivation time, including SiO2 doping ratio on the wettability and corrosion resistance of the prepared surfaces are investigated. The results demonstrate that the surface exhibits a micro–nano multilayer and modified nano‐multiscale cluster structure which has a contact angle (CA) of 155.8 ± 1.7° and a sliding angle (SA) of 5 ± 0.5° by employing the following conditions: hydrochloric acid etching time of 10 min, hydrofluoric acid etching time of 25 min, passivation time of 300 min, and a 3 wt% SiO2 doping ratio. Moreover, the surface displays extremely weak droplet adhesion and excellent self‐cleaning properties. Furthermore, the corrosion inhibition of the prepared steel surface is evaluated using potentiodynamic polarization curves and electrochemical impedance spectroscopy. The results indicate that the corrosion inhibition efficiency of the superhydrophobic surface is enhanced by about 89.95% compared to the traditional two‐step processing involving etching and modification. These findings expand the potential applications of steel.