Fabrication and characterizations of Ho3Sc2Al3O12 magneto‐optical transparent ceramics

Abstract

AbstractCurrently, Faraday isolators and rotators for high‐power lasers are popular research topics; therefore, finding magneto‐optical materials with excellent Verdet constants and thermal properties is crucial. In this study, novel holmium scandium aluminum garnet (HoSAG) magneto‐optical ceramics were fabricated using vacuum sintering. This study improved the traditional ball milling method and pre‐synthesized powders with great sinterability after secondary ball milling and sieving. Different pre‐synthesis temperatures were found to have significant effects on the particle size and micromorphology of the synthesized powders. HoSAG ceramics with 0.05 wt% MgO sintering aid and held at 1700°C for 30 h reached a transmittance of 76.7% at 1550 nm. Meanwhile, HoSAG transparent ceramics maintain higher transmittance in the infrared region (>1500 nm) than terbium gallium garnet (TGG) crystals, indicating better application prospects. The Verdet constants of HoSAG magneto‐optical ceramics at 405, 532, 808, and 1064 nm were −421.5, −181.2, −65, and −32.3 rad T−1 m−1, respectively, which are slightly less than those of TGG magneto‐optical ceramics. Moreover, the thermal conductivity of HoSAG ceramics at 300.00 K was 4.89 W m−1 K−1, which is comparable to that of the TGG ceramics.