Fabrication and Characterization of TiO<sub>2</sub>-Doped ZnAl<sub>2</sub>O<sub>4</sub> Nanocrystals via Sol-Gel Method for GPS Antenna

Abstract

The Zn(1-x)TixAl2O4 (x = 0.00, 0.05, 0.15 & 0.25) nanocrystals thin films were prepared by sol-gel method. The properties of Zn(1-x)TixAl2O4 were investigated by X-ray diffraction (XRD), Atomic Force Microscope (AFM), Fourier transform infrared spectra (FTIR) and (UV-Vis). By indexing the XRD patterns, we identified three structural types which is ZnAl2O4, anatase and rutile. The addition of TiO2 increased the crystallite size from 14.65 to 25.25 nm. The direct band gap was found to be around 3.35 to 3.84 eV. The addition of TiO2 increased the crystallite size, surface roughness, and lattice parameters of the resultant films, evidently affecting their density and dielectric constant (). The thin films were characterized in the certain frequency to determine the using LCR spectrometer. The and density value of the Zn(1-x)TixAl2O4 films increase linearly from 8.56 to 13.48 and 4.60 to 4.70 g/cm3 with the increasing of x value, respectively. Based on the material analysis and microwave antenna theory, GPS patch antennas were fabricated using the Zn(1-x)TixAl2O4 material. The fabricated GPS antenna with the highest (13.48) material exhibits the smallest size of antenna which is 7.45 cm2. The performances and the operating frequencies were measured using a PNA series network analyzer. The result showed that all patch antennas operate at frequency of 1.570 GHz. The GPS patch antenna fabricated from Zn0.25Ti0.75Al2O4 showed an excellent combination of return loss (-29.6 dB), smallest size (7.85 cm2), and wide bandwidth (195 MHz). All fabricated antennas are meets the requirements of GPS applications.