Abstract

The chemical composition of standard Inconel 740 superalloy was modified by changes in the Al/Ti ratio (0.7, 1.5, 3.4) and addition of Ta (2.0, 3.0, 4.0%). Remelted Inconel 740 (A0) and nine variants with various chemical compositions were fabricated by lost-wax casting. The microstructure, microsegregation, phase transformation temperatures, thermal expansion coefficients and hardness of the superalloys were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, differential scanning calorimetry, dilatometry and Vickers measurements. Typical dendritic microstructure was revealed with microsegregation of the alloying elements. Segregation coefficient ki for Ti, Nb and Ta did not exceed unity, and so precipitates enriched mainly in these elements were found in interdendritic spaces. The Nb-rich blocky precipitates, MC carbides, MN nitrides, oxides, and fine γ’ was in all modified castings. Presence of other microstructural features, such as Ti-rich needles, eutectic γ-γ’ islands, small Al-rich and Cr-rich precipitates depended on the casting composition. The lowest solidus and liquidus temperatures were observed in superalloys with a high Al/Ti ratio. Consequently, in A7–A9 variants, the solidification range did not exceed 100 °C. In the A0 variant the difference between liquidus and solidus temperature was 138 °C. Hardness of all modified superalloys was at least 50% higher than for the remelted Inconel 740 (209 HV10).

Highlights

  • Electricity is presently a key pillar of mankind’s living and economic development

  • Due to environmental restrictions having increased in recent years, new advanced ultra-supercritical (A-USC) plants ensure presently higher efficiencies compared to conventional fossil-burning power

  • Nine newly-developed superalloys based on Inconel 740 were fabricated by investment casting in

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Summary

Introduction

Despite various methods of electricity production, a significant part of the energy sector is still based on coal. Forecasts predict that this state will continue for the decades, despite the continuously repeated economic crises in the oil & gas branch. The factor that can successfully mitigate the effects of such crises is the continuous improvement of power unit efficiency. This has prompted the power sector to increase the pressure and temperature of their steam boilers to reduce CO2 , NOx , and SOx emissions [1,2,3,4].

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