Fabrication and characterization of Pb1−xYbxTe-based alloy thin-film thermoelectric generators grown by thermal evaporation technique

Abstract

In this study p-Pb0.925Yb0.075Te:Te and n-Pb0.94Yb0.06Te powders synthesized by solid-state microwave technique were used to fabricate thermally evaporated thin films. The nanostructure and composition of the films were studied using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray spectroscopy (EDX). Electrical characterizations of the as-deposited films in terms of the Seebeck coefficient and electrical conductivity and power factor were conducted at a range of 298K to 523K. The microthermoelectric devices were composed of 20-pair and 10-pair p-Pb0.925Yb0.075Te:Te and n-Pb0.94Yb0.06Te thin films on glass substrates. The dimensions of the thin-film thermoelectric generators, which consisted of 20-pair and 10-pair legs connected by aluminum electrodes, were 23mm×20mm and 12mm×10mm, respectively. The 20-pair p–n thermocouples in series generated a maximum open-circuit voltage output (Voc) of 0.581V and a maximum output power of 25.87×10−8W at a temperature difference ΔT=164K, whereas the 10-pair p–n thermocouples generated 0.311V and 13.71×10−8W maximum Voc and maximum output power, respectively, at ΔT=164K.