Fabrication and characterization of NiCu/GO and NiCu/rGO nanocomposites for fuel cell application.

Abstract

This study investigated the electrochemical behavior of NiCu, NiCu/GO, and NiCu/rGO nanocomposites designed by combining a modified Hummers' method and hydrothermal technique. The prepared nanocomposites are tested as electrocatalysts in direct alcohol oxidation fuel cells (DAFCs) to identify the role of GO and rGO as catalyst supports for the enhancement of the NiCu composite performance. The production of the NiCu/GO and NiCu/rGO composites was demonstrated by FTIR spectroscopy, EDX, and SEM analyses. In DAFCs experiments, NiCu/rGO has better catalytic activity than pure NiCu and NiCu/GO composites, whereas the use of rGO and GO as supports enhances the performance of NiCu by 468.2% and 377.7% in methanol and 255.6% and 105.9% in ethanol, respectively. The higher performance was caused by the increased density of active dots and the combined electronic effects in the designed catalysts. The stabilities of the catalysts and charge carriers' dynamics are studied using chronoamperometry and electrochemical impedance spectroscopy.