Fabrication and characterization of new Fe3O4@SiO2@TiO2-CPTS-HBAP (FST-CH) nanoparticles for photocatalytic degradation and adsorption removal of rhodamine B dye in the aquatic environment

Abstract

In this study, Fe3O4@SiO2@TiO2-CPTS-HBAP (FST-CH) nanoparticle was prepared for the simultaneous adsorption and photocatalytic degradation of aromatic chemical pollutants (Rhodamine B dye) in aqueous solution. FST-CH nanoparticle was characterized using scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), Energy Dispersive X-Ray (EDX) Fluorescence Spectrometer and X-Ray Diffraction (XRD) spectroscopy. The photocatalytic activity of rhodamine B dye (RhB) was evaluated with a Kerman UV 8/18 vertical roller photoreactor. About 56% of RhB in aqueous medium was adsorbed by FST-CH nanoparticles with only 45 min of stirring in the dark, and about 77.01% was degraded or converted to other structures under the photoreactor for 120 min. The photocatalytic degradation of RhB (apparent rate constant: 0.0026 mg dm-3 min-1) occurred by a pseudo-second order reaction. In addition, the recovery of the prepared magnetic FST-CH nanoparticle by an external magnetic field, exhibiting good magnetic response and reusability, shows that the obtained magnetic FST-CH nanoparticle is stable and maintains high degradation ratio and catalyst recovery even after four cycles. Thus, the prepared FST-CH nanoparticle can be highly recommended for its use in potential applications of water decontamination.