Fabrication and characterization of a bifunctional zinc oxide/multiwalled carbon nanotube/ poly(3,4-ethylenedioxythiophene): Polystyrene sulfonate composite thin film

Abstract

Hybrid thin film sensors based on semiconductor oxides and carbon nanostructures are promising materials to improve the sensing, thermomechanical and optical properties. In this study, a thin film based on a composite from ZnO nanoparticles, milled multiwalled carbon nanotubes, and conducting polymer was fabricated. The layer was spray-coated to the surface of amorphous polyethylene terephthalate substrate. The hybrid layer and components have been systematically characterized by transmission and scanning electron microscopy, dynamic light scattering and the optical absorption spectrum was observed by ultraviolet-visible spectroscopy. The change in glass transition temperature was measured by dynamic mechanical analysis. Gas sensing tests reveal that the ZnO/multiwalled carbon nanotube/ poly(3,4-ethylenedioxythiophene): polystyrene sulfonate film on amorphous polyethylene terephthalate has remarkably enhanced performance compared to the same layer on indium tin oxide /polyethylene terephthalate. It could detect ethanol vapor in a wide concentration range with good response, fast recovery, and repeatability at room temperature. The layer was also tested as an ultraviolet photodetector, showing a promising signal. These features indicate the composite usability in further sensor applications.