Fabrication and characteristics of Li2TiO3 pebbles manufactured by using powder injection molding (PIM) process

Abstract

The solid type of tritium breeder materials is usually used in a pebble form because of the high packing factor, efficiency of tritium extraction, and advantage of thermal conduction between the structural materials. The breeder pebbles are required a good sphericity and uniform microstructure from the viewpoint of a packing factor and a release of bred tritium. Therefore, in this study, the lithium metatitanate (Li2TiO3) pebbles have been fabricated by powder injection molding process in order to secure a high sphericity of pebbles. In addition, the physical, mechanical, and thermal properties of the pebbles have been investigated. The Li2TiO3 green pebbles have been fabricated by using the powder injection molding process (PIM process). The diameter and sphericity of green pebbles were about 1.000 mm and 1.001, respectively. Then, the green pebbles were sintered at 1000 °C for 3 hr in air atmosphere. The diameter of sintered pebbles is about 0.95 mm. The volume shrinkage ratio was about 16 % during the sintering process. The uniform microstructure with open pores on the inside and outside of the sintered pebbles was observed.