Fabricating Materials of Institute Lavoisier-53(Fe)/zeolite imidazolate framework-8 hybrid materials as high-efficiency and reproducible adsorbents for removing organic pollutants

Abstract

Environmental pollution by emerging contaminants has become an urgent problem. Herein, novel binary metal–organic framework hybrids were constructed from Materials of Institute Lavoisier-53(Fe) (MIL-53(Fe)) and zeolite imidazolate framework-8 (ZIF-8) for the first time. A battery of characterizations were employed to determine the MIL/ZIF hybrids' properties and morphology. Furthermore, the MIL/ZIF towards toxic antibiotics (tetracycline, ciprofloxacin and ofloxacin) were studied to explore their adsorption abilities. The present work disclosed that the obtained MIL-53(Fe)/ZIF-8 = 2:3 possessed an eminent specific surface area with an admirable removal efficiency of tetracycline (97.4%), ciprofloxacin (97.1%) and ofloxacin (92.4%), respectively. The tetracycline adsorption process conformed to the pseudo-second-order kinetic model and this process was more compatible with the Langmuir isotherm model with the highest adsorption capacity of 215.0 mg g−1. Moreover, the process of removing tetracycline was proved to be spontaneous and exothermic by the thermodynamic results. Furthermore, the MIL-53(Fe)/ZIF-8 = 2:3 towards tetracycline exhibited significant regeneration ability. The effects of pH, dosage, interfering ions and oscillation frequency on tetracycline adsorption capacity and removal efficiency were also investigated. The primary factors contributing to the decent adsorption ability between MIL-53(Fe)/ZIF-8 = 2:3 and tetracycline included electrostatic, π–π stacking, hydrogen bonding and weak coordination interactions. Additionally, we also investigated the adsorption ability in real wastewater. Thus, the proposed binary metal–organic framework hybrid materials can be deemed a promising adsorbent in wastewater purification.