Abstract
Large-scale and low-cost synthesis of covalent organic frameworks (COFs) to meet the demands of industrial application remains formidably challenge. Here we report using 2,4,6-collidine as monomer to produce a series of highly crystalline olefin-linked COFs by a melt polymerization method. This method enables the kilogram-scale fabrication of self-shaped monolithic robust foams. The afforded COFs possess extremely low cost (<50 USD/kg), superior to all the reported COFs. Furthermore, using one-pot or post-modification methods can conveniently transform neutral COFs to ionic COFs, which can be applied as highly efficient ion-exchange sorbents for scavenging oxoanion pollutants. Remarkably, the superior adsorption capacity of a model oxoanion (ReO4 - ) is the highest among crystalline porous materials reported so far. This work not only expands the scopes of olefin-linked COFs but also enlightens the route for the industrial production of crystalline ion exchange sorbents.
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