Fabricating a visibly colorimetric film via self-releasing of anthocyanins from distributed mulberry pomace particles in hydrophilic sodium carboxymethyl starch-based matrix to monitor meat freshness

Abstract

A highly distinguishable indicator film was developed based on sodium carboxymethyl starch, κ-carrageenan, carboxylated cellulose nanocrystals and mulberry pomace particles (MPPs). As the content of MPPs increased from 0 % to 6 %, the tensile strength decreased from 11.71 MPa to 5.20 MPa, the elongation at break increased from 26.84 % to 43.76 %, respectively, and the haze increased from 34.12 % to 52.10 %. The films accurately exhibit a color change from purple to blue-green under alkaline conditions. The enhanced haze improved the visible resolution of the films during the color-changing process. The films with the size of 7.50 mm × 7.50 mm and 10.0 mm × 10.0 mm exhibited obvious color changes when the total volatile basic nitrogen reached 14.60 mg/100 g and 19.04 mg/100 g, respectively, which accurately indicated the quality of pork and fish. This study will offer a simplified path to improve both accurate sensitivity and distinguishability for smart films.