Extremely low coercivity of powder Co-rich amorphous alloy obtained by gas atomisation

Abstract

A novel Co-base soft magnetic powder with ultra-low coercivity was produced by inert gas atomisation. The as-atomised powder is fully amorphous owing to its high glass forming ability and the proper selection of atomisation conditions; it exhibits a very low coercivity (0.130Oe) mainly due to the low magnetostriction coefficient of Co-based alloys. After production, the powder was annealed at different temperatures between 300 and 600 ºC for 30minutes. Crystallisation started at around 575 ºC, which is the temperature of the first exothermic peak detected by differential scanning calorimetry. Annealing the powder at temperatures below 550 ºC develops only structural relaxation of the amorphous structure. The smallest coercivity (0.056Oe) was found in the sample annealed at 400 ºC. On the other hand, an increment of the coercivity of four orders of magnitude occurred after full crystallisation at 600 ºC (394.320Oe). From the analysis of the curves of anisotropy field distribution, it can be concluded that this Co-base alloy shows lower average anisotropy field, a more gaussian shape and a wider distribution than Fe-base alloys. This is explained by a lower magnetoelastic anisotropy and a more homogeneous distribution of the magnetic anisotropy. The powder exhibits a spherical shape that makes it very suitable as ferromagnetic phase to manufacture powder cores with extremely low hysteresis loss for medium-high frequency applications.