Abstract

Photoisomerization: N-phenylcarbazole-conjugated dimethyl 2,3-diethynylfumarate/maleate, E/Z-4, shows highly efficient and reversible visible-light E/Z photoisomerization (Φtotal=0.40) upon excitation with an intramolecular charge-transfer band. This photochromism induces switching of electronic communication between the two N-phenylcarbazole moieties in the one-electron oxidized mixed-valent state (see scheme).

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