Abstract

The extraction of REEs(III), U(VI), and Th(IV) from nitric acid solutions with solutions of diphenyl(dialkylcarbamoylmethyl)phosphine oxides is considerably enhanced in the presence of an ionic liquid, 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide. The extraction efficiency varies in a wide range depending on substituents at the P and N atoms and on the structure of the fragment linking the coordinating groups in the extractant molecule.

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