Abstract

This research work focuses on the removal of phenol using a flat sheet supported liquid membrane impregnated with triglycerides (vegetable oils). The mass transfer of phenol was found to be dependent on various factors such as type of vegetable oil, support material, feed phase pH and concentration, stripping phase concentration and stirring speed. The phenol transport was found to be higher when PTFE membrane (pore size 0.45 μm) impregnated with coconut oil was used and mass transfer coefficient was found to be 3.50 × 10-6 m/s. The corresponding stirring speed, pH of feed solution, concentration of stripping (NaOH) solution were 350 rpm, 4.0 and 0.2 M, respectively. The 92.5% of phenol was extracted from feed phase to stripping phase in 20 h. The aqueous boundary layer thickness reduced with an increase in stirring speed up to a certain extent (350 rpm), beyond which, it resulted in turbulence leading to displacement of impregnated oil from membrane pores. Phenol can be transported through the membrane, ...

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