Abstract
Measurement of the extraction equilibrium of silver(I) from nitric acid and aqueous ammonium nitrate solutions with triisobutylphosphine sulfide (TBPS) in toluene was carried out at 303 K to examine the effects of the concentrations of nitrate and hydrogen ions and silver in the aqueous phase as well as that of the extractant. It was found that the extraction equilibrium is explained in terms of the solvation of silver(I) by TBPS with simultaneous transfer of a nitrate ion into the organic phase to form an ion-pair and that the extracted species in the organic phase is the sliver: TBPS 1:2 complex.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
