Extraction and Recovery of Metals from Spent HDS Catalysts: Lab- and Pilot-Scale Results of the Overall Process

Abstract

The present study proposes an overall recycling process for spent hydrodesulfurization (HDS) catalysts. The process put together stages already known in the technical literature, tested again with samples coming from the roasting stage in a pilot kiln, which is the most limiting stage of metal recovery from spent catalysts. These catalysts contain valuable metals like cobalt (Co), molybdenum (Mo), nickel (Ni), and vanadium (V). In particular, one Co-Mo catalyst was treated in order to optimize the roasting step (time, soda ash, and temperature) at a pilot scale and thus maximize the extraction yield of molybdenum (Mo) and vanadium (V). In particular, a dry Co-Mo catalyst was used. After roasting at 700 °C for 2.5 h, the best conditions, the catalysts underwent water leaching, separating Mo and V from Co and the alumina carrier, which remained in the solid residue. The pregnant solution was treated to remove arsenic (As) and phosphorus (P), representing the main impurities for producing steel alloys. V was precipitated as NH4Cl, and further calcined to obtain commercial-grade V2O5, whereas Mo was recovered as molybdic acid by further precipitation at a pH of around one. Thus, molybdic acid was calcined and converted into commercial-grade MoO3 by calcination. The hydrometallurgical section was tested on a lab scale. The total recovery yield was nearly 61% for Mo and 68% for V, respectively, compared with their initial concentration in the spent Co-Mo catalysts.