Extraction and characterization of highly pure alumina (α, γ, and θ) polymorphs from waste beverage cans: A viable waste management approach

Abstract

The recycling and recovery of important materials from inexpensive feedstock has now become an intriguing area and vital from commercial and environmental viewpoints. In the present work, extraction of different single phases of alumina (α, γ, θ-Al2O3) having high purity (>99.5 %) from locally available waste beverage cans (∼95 % Al) through facile precipitation route calcined at distinct temperatures has been reported. The optimization of process technology was done by a variety of different synthesis parameters, and the production cost was estimated between 84.47-87.45 USD per kg of alumina powder. The as prepared alumina fine particles have been characterized using different sophisticated techniques viz. TG-DTA, WD-XRF, XRD, FT-IR, SEM, DLS-based particle size analysis (PSA) with zeta (ζ) potential measurement and UV–Visible Spectroscopy. X-ray diffractogram confirms the formation of γ-, θ-, and α-alumina at 500–700 °C, 900–1000 °C, and 1200 °C respectively and crystallite size, crystallinity, strain, dislocation density, and specific surface area were measured using major X-ray diffraction peaks which varies with temperature. The SEM studies showed that the as prepared alumina particles were agglomerated, irregular-shaped with particle size (0.23–0.38 µm), pore size, and porosity were calculated from SEM image. ζ-potentials at different pH values as well as isoelectric point (IEP) of α, γ, and θ alumina were calculated in an aqueous medium which changes with temperature. The direct band gap (Eg) energies were found between 4.09 and 5.19 eV of alumina obtained from different calcination temperatures. The synthesized materials can be used in sensors, ceramics, catalysis, and insulation applications.