Abstract
The semi-empirical model of Miedema and Van der Woude is used to extract information from Mossbauer isomer shift data about the packing in amorphous FexB1-x-alloys (10at%<x<90at%). At the iron-rich side the samples have an open structure, which changes to a strained one at the boron-rich side. The predicted increased Fe-Fe distance in a-Fe50B50 was verified by energy-dispersive X-ray diffraction.
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