Extracting Physical Information from the Voigt Profile Using the Lambert W Function

Abstract

Spectral line shapes are a key ingredient of hot-plasma opacity calculations. Since resorting to elaborate line-shape models remains prohibitive for intensive opacity calculations involving ions in different excitation states, with L, M, etc., shells are populated, and Voigt profiles often represent a reliable alternative. The corresponding profiles result from the convolution of a Gaussian function (for Doppler and sometimes ionic Stark broadening) and a Lorentzian function, for radiative decay (sometimes referred to as “natural” width) and electron-impact broadening. However, their far-wing behavior is incorrect, which can lead to an overestimation of the opacity. The main goal of the present work was to determine the energy (or frequency) at which the Lorentz wings of a Voigt profile intersect with the underlying Gaussian part of the profile. It turns out that such an energy cut-off, which provides us information about the dominant line-broadening process in a given energy range, can be expressed in terms of the Lambert W function, which finds many applications in physics. We also review a number of representations of the Voigt profile, with an emphasis on the pseudo-Voigt decomposition, which lends itself particularly well to cut-off determination.