Abstract
Presented here are two new open-framework metal sulfate-oxalates, formulated as H2hpip·Mn2(SO4)(C2O4)2(H2O) (SCU-14) and (Hthfa)2·In2(SO4)(C2O4)3·2H2O (SCU-16), where hpip = homopiperazine and thfa = tetrahydrofurfurylamine. SCU-14 has a diamondoid framework with extra-large 14-ring channels. SCU-16 has a zeolitic ABW topology with extra-large 16-ring channels. The temperature dependence of the magnetic susceptibility of SCU-14 was also investigated.
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