Extra CO2 capture and storage by carbonation of biomass ashes

Abstract

Eight biomass ashes (BAs) produced at 500 and 900 °C were studied to definite their composition, phase transformations, carbonation-decarbonation behavior, and CO2 capture and storage (CCS) potential. Light microscopy, powder X-ray diffraction, scanning electron microscopy, as well as differential-thermal, thermo-gravimetric and chemical analyses were used for that purpose. It was found that most of the BAs studied have high contents of alkaline-earth and alkaline elements represented by carbonates, bicarbonates, oxyhydroxides, chlorides, sulphates, phosphates, and inorganic amorphous material, and such minerals and phases have a key role for CCS by BA. There is an intensive formation of newly formed carbonates as a result of solid–gas reactions between alkaline-earth and alkaline oxyhydroxides and volatile CO2 formed during biomass combustion. Subsequently, additional post-combustion carbonates and bicarbonates are formed by both solid–gas and solid-liquid reactions between the unreacted oxyhydroxides and carbonates in BA and CO2 occurring in air and water during BA storage. The decomposition temperature of carbonates is mostly at 600–900 °C and the mass loss measured in this temperature range approximately determines the CO2 volatilization from the carbonates in BAs. The measured CO2 volatilization (or CCS) for the BAs studied is between 1 and 27% (mean 11%). It was emphasized that the biomass energy can be not only carbon-neutral, but also with some extra CCS potential due to fixation and immobilization of atmospheric CO2 in BA. Therefore, the future large-scale bioenergy production can contribute enormously for reducing CO2 emissions and can decrease or eliminate the application of expensive technologies for CCS.